Eco-friendly smart hydrogels for soil conditioning and sustain release fertilizer     

J. Pushpamalar  S. J. Langford  M. B. Ahmad  Y. Y. Lim  K. Hashim 《International Journal of Environmental Science and Technology》2018,15(10):2059-2074

In the agricultural industry, biomass waste generated along with the production of food, is transformed into value-added products. Also, the demand for the slow or control release fertilizer is increasing to reduce the cost of maintaining the agricultural land. These issues are tackled by converting biomass waste to a slow fertilizer release vehicle and biodegradable water retention material that could reduce the cost for fertilizer application and simultaneously preserved the soil from dryness. A series of carboxymethyl sago pulp (CMSP) hydrogels were prepared by electron beam irradiation. Slow release systems were evaluated by loading potassium nitrate (KNO₃) and ammonium nitrate (NH₄NO₃) into the CMSP hydrogels. These CMSP hydrogels endow slow release property, biodegradability and a soil moisture preservation property that could find greener application in agricultural industries. The results indicate that CMSP hydrogels have a great potential as an agent for slow release of fertilizers.  相似文献   

Interactive effect of cadmium and zinc on chromium uptake in spinach grown in Vertisol of Central India     

M. L. Dotaniya  S. Rajendiran  M. Vassanda Coumar  V. D. Meena  J. K. Saha  S. Kundu  A. Kumar  A. K. Patra 《International Journal of Environmental Science and Technology》2018,15(2):441-448

A pot culture experiment was conducted to study impact and interaction of multi-metals on growth, yield and metals uptake by spinach (variety All Green). Three levels of each chromium (0, 50 and 100 mg/kg), cadmium (0, 1 and 2 mg/kg) and zinc (0, 10 and 20 mg/kg) in combinations (total treatments 3 × 3 × 3 = 27) were applied in a Vertisol (5 kg). The results showed that increasing the concentration of chromium, cadmium and zinc in soil enhanced the respective metal concentrations in spinach root and shoot. When cadmium at 2 mg/kg along with chromium at 100 mg/kg soil was applied, chromium concentration and uptake were decreased in root and shoot. Meanwhile, zinc application had no significant effect on chromium uptake and concentration in spinach biomass. From the results, it was concluded that cadmium at higher dose had an antagonistic effect over chromium. On the other hand, in chromium, cadmium and zinc combinations particularly at their higher levels, a competition among each other was found. Therefore, the findings could be used as guidelines for controlling and management of heavy metals pollution in farmland.  相似文献   

Recent insights into the dissolved and particulate fluxes from the Himalayan tributaries to the Ganga River     

Md Maroof Azam  Monika Kumari  Chinmaya Maharana  Abhay K. Singh  Jayant K. Tripathi 《Environmental Earth Sciences》2018,77(8):313

The Ganga River plays a major role in the transfer of materials from the Indian sub-continent to the Bay of Bengal, both in dissolved and particulate forms. To understand the present elemental dynamics of the Ganga River system, it is important to assess the hydrogeochemical contribution of its tributaries. In this paper, we present an updated database on dissolved and particulate fluxes and denudation rates of the Himalayan tributaries of the Ganga River (Ramganga, Ghaghara, Gandak and Kosi). Dissolved trace element concentrations, their fluxes and suspended sediment-associated elemental fluxes of the Himalayan tributaries have been reported for the first time. Total dissolved flux of the Ramganga, Ghaghara, Gandak and Kosi was estimated as 4, 19.1, 10.3 and 8.8 million tons year^?1 accounting for ~?5.7, ~?27.3, ~?14.7 and ~?12.6%, respectively, of the total annual dissolved load carried by the Ganga River. The total particulate flux of the Ramganga, Ghaghara, Gandak and Kosi was computed as 8.2, 81.6, 30.9 and 19.5 million tons year^?1, respectively. Compared to earlier studies, we have found a significant increase in the total dissolved flux and chemical denudation rate of the studied tributaries. The estimated particulate fluxes were found to be low in comparison to the previous studies. We suggest that a significant increase in the dissolved fluxes and a decrease in the particulate fluxes are an indication of the increasing anthropogenic disturbances in the catchment of these tributaries.  相似文献   

Non-woven polypropylene fabric modified with carbon nanotubes and decorated with nanoakaganeite for arsenite removal     

J. Tomaszewska  P. Smektała  I. Zgłobicka  J. Michalski  K. J. Kurzydłowski  P. Krzemiński  C. Escudero-Oñate 《International Journal of Environmental Science and Technology》2018,15(9):1831-1842

Due to its harmful impact on human health, the presence of heavy metals, metalloids and other toxic pollutants in drinking or irrigation water is a major concern. Recent studies have proved that nanosized adsorbents are significantly more effective than their microsized counterparts. Particular attention has been given to nanocomposites with nanoadsorbents embedded in matrixes that could provide stability to the material and contribute to eliminating problems that may appear when using conventional granular systems. This study presents the preparation of a novel hybrid filter from a commercially available polypropylene (PP) non-woven fabric matrix modified with multiwall carbon nanotubes (MWCNT) and iron oxy(hydroxide) nanoparticles, and its use in the removal of As(III). A Box–Behnken statistical experimental design has been chosen to explore relevant variables affecting the filter performance: (1) As(III) concentration, (2) pH and (3) sorbent dose. From an As(III) concentration of 10 mg L^?1, at pH 6.5 and with a sorbent dose of 5 g L^?1, the PP filter modified with MWCNT removes 10% of the initial metalloid concentration, reaching a capacity of 0.27 mg g^?1. After modification with iron oxy(hydroxide), the performance of the material is largely enhanced. The filter, under the same conditions, removes 90% of the initial As(III) concentration, reaching a capacity almost tenfold higher (2.54 mg g^?1). This work demonstrates that the developed hybrid filter is effective toward the removal of As(III) in a wide range of pHs. A cubic regression model to compute the removal of the filter as a function of pH and sorbent dose is provided.  相似文献   

Assessment of soil erosion in a tropical mountain river basin of the southern Western Ghats,India using RUSLE and GIS   总被引：1，自引：0，他引：1  

Jobin Thomas  Sabu Joseph  K.P.Thrivikramji 《地学前缘(英文版)》2018,9(3):893-906

Revised Universal Soil Loss Equation(RUSLE) model coupled with transport limited sediment delivery(TLSD) function was used to predict the longtime average annual soil loss, and to identify the critical erosion-/deposition-prone areas in a tropical mountain river basin, viz., Muthirapuzha River Basin(MRB; area=271.75 km~2), in the southern Western Ghats, India. Mean gross soil erosion in MRB is 14.36 t ha~(-1) yr~(-1), whereas mean net soil erosion(i.e., gross erosion-deposition) is only 3.60 t ha~(-1) yr~(-1)(i.e., roughly 25% of the gross erosion). Majority of the basin area(~86%) experiences only slight erosion(5 t ha~(-1) yr~(-1)), and nearly 3% of the area functions as depositional environment for the eroded sediments(e.g., the terraces of stream reaches, the gentle plains as well as the foot slopes of the plateau scarps and the terrain with concordant summits). Although mean gross soil erosion rates in the natural vegetation belts are relatively higher, compared to agriculture, settlement/built-up areas and tea plantation, the sediment transport efficiency in agricultural areas and tea plantation is significantly high,reflecting the role of human activities on accelerated soil erosion. In MRB, on a mean basis, 0.42 t of soil organic carbon(SOC) content is being eroded per hectare annually, and SOC loss from the 4th order subbasins shows considerable differences, mainly due to the spatial variability in the gross soil erosion rates among the sub-basins. The quantitative results, on soil erosion and deposition, modelled using RUSLE and TLSD, are expected to be beneficial while formulating comprehensive land management strategies for reducing the extent of soil degradation in tropical mountain river basins.  相似文献   

Removal of diazinon pesticide from aqueous solutions using MCM-41 type materials: isotherms,kinetics and thermodynamics     

M. A. Amani  A. M. Latifi  K. Tahvildari  R. Karimian 《International Journal of Environmental Science and Technology》2018,15(6):1301-1312

In this research, ordered mesoporous silica, including MCM-41, was synthesized via sol–gel process and a propyl methacrylate-modified ordered mesoporous silica (MPS-MCM-41) was successfully synthesized via a postsynthesis grafting process. Then both MCM-41 and MPS-MCM-41 were characterized using FTIR, XRD, SEM and BET techniques. The synthesized materials were utilized as adsorbent for removal of diazinon pesticide from aqueous solutions. The effects of pH, contact time, adsorbent dose, initial concentration and temperature have been evaluated using removal efficiencies. Also, the kinetic, thermodynamic and isotherm models of diazinon adsorption were studied for the both MCM-41 and MPS-MCM-41. The results showed that the maximum adsorption capacities are 142 and 254 mg g^?1 for the MCM-41 and MPS-MCM-41, respectively, at the initial concentration of 50 mg L^?1, temperature of 298 K and adsorbent dose of 0.1 g L^?1. The highest percentages of diazinon removal are 56.4 and 87.2 (at adsorbent dose of 2 g L^?1 and the temperature of 318 K) for the MCM-41 and MPS-MCM-41, respectively. The Freundlich and Langmuir models are more compatible for describing equilibrium data of the diazinon adsorption capacity on the MCM-41 and MPS-MCM-41, respectively. Thermodynamic study indicated that the adsorption process of diazinon onto MCM-41 and MPS-MCM-41 is exothermic and has a spontaneous nature. The higher adsorption capacity and higher spontaneous nature of MPS-MCM-41 in comparison with MCM-41 might be due to the presence of the both hydrogen bonding and hydrophobic interaction between surface functional groups of MPS-MCM-41 (hydroxyl and propyl methacrylate) and diazinon functional groups.  相似文献   

Preservation of thermophilic mixed culture for anaerobic palm oil mill effluent treatment by convective drying methods     

D. T. Tan  S. K. Chin  P. E. Poh  Y. H. Lee 《International Journal of Environmental Science and Technology》2018,15(6):1211-1222

The generation of huge amount of liquid waste known as palm oil mill effluent is a major problem in oil palm industry. Meanwhile, anaerobic biodegradation of such organic effluent at thermophilic condition is a promising treatment technology due to its high efficiency. However, storage and transportation of thermophilic mixed culture sludge are challenging due to constant biogas generation and heating requirement. Hence, drying of thermophilic sludge was conducted to obtain dormant thermophiles and thus enables easier handling. In this study, thermophilic sludge was dried using heat pump at 22 and 32 °C as well as hot air oven at 40, 50, 60, and 70 °C. Subsequently, quality of dried sludge was examined based on most probable number enumeration, chemical oxygen demand, and methane yield. Average drying rate was found to increase from 3.21 to 17.84 g H₂O/m² min as drying temperatures increases while average moisture diffusivity values ranges from 5.07 × 10^?9 to 4.34 × 10^?8 m²/s. Oven drying of thermophilic mixed culture resulted in highest chemical oxygen demand removal and lowest log reduction of anaerobes at 53.41% and 2.16, respectively, while heat pump drying resulted in the highest methane yield and lowest log reduction of methanogens at 53.4 ml CH₄/g COD and 2.09, respectively. To conclude, heat pump at 22 °C was most suitable drying technique for thermophilic mixed culture as the original methane-producing capability was largely retained after drying, at a slightly lower yet still comparable chemical oxygen demand removal when palm oil mill effluent was treated with the rehydrated culture.  相似文献   

A micromechanical experimental study of highly/completely decomposed tuff granules     

C. S. Sandeep  M. C. Todisco  V. Nardelli  K. Senetakis  M. R. Coop  S. D. N. Lourenco 《Acta Geotechnica》2018,13(6):1355-1367

In this paper, an experimental micromechanical study is presented investigating the contact mechanics and tribological behaviour of highly/completely decomposed tuff granules. The parent material was taken from two locations—named the top and bottom—from a recent landslide in Hong Kong, and in this study the tested granules were obtained from the parent material after drying and sieving processes. Basic material characterisation was conducted quantifying the particle shape, the surface roughness and the strength of a set of grains. A set of twenty-nine monotonic inter-particle shearing tests were conducted on pairs of granules taken from the top and bottom of the landslide. It was found that the granules had very high friction angles at their contacts, in general greater in comparison with other materials reported in the literature. The slightly greater inter-particle friction for the granules taken from the top of the landslide might be because of their higher roughness in comparison with the ones from the bottom. Additional experiments were conducted to investigate the normal and tangential load–displacement response of the granules subjected to cyclic loading. A good curve fitting for the normal load–displacement response could be obtained by using very low apparent Young’s moduli in the Hertzian model. In general, the decomposed tuff granules showed significant plastic response during the first normal load cycle, and this plastic behaviour continued for the subsequent third and fourth cycles. In the cyclic inter-particle shearing tests, the nonlinearity and hysteresis increased for larger cyclic displacements, but the effect of the number of shearing cycles on the energy loss was generally small. Finally, a limited discussion is presented on the applicability of a theoretical model on the tangential load–displacement behaviour of the granules.  相似文献   

Lajishan accretionary complex: Implications for Paleozoic accretionary and collisional events in the South Qilian belt     

YAN Zhen  FU Changlei  Jonathan AITCHISON  Solomon BUCHMON  NIU Manlan 《《地质学报》英文版》2018,92(Z2):41-41

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Rupture of the Indian slab in the 2011 Mw 6.9 Sikkim Himalaya earthquake and its tectonic implications     

T. C. Sunilkumar  Anil Earnest  K. Silp  Ronia Andrews 《《地质学报》英文版》2018,92(Z1):58-58

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